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47655 Aldrich

Bis(phenylthio)methane

≥98.0% (GC)

Synonym: Diphenylthiomethane, Formaldehyde diphenyl mercaptal

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfides/Disulfides, Sulfur Compounds More...
InChI Key   ZHUPZVIALZHGGP-UHFFFAOYSA-N
assay   ≥98.0% (GC)
bp   194 °C/8 mmHg(lit.)
mp   34-37 °C(lit.)

Description

Other Notes

Acyl anion equivalent with some advantages over 1,3-dithiane; for the preparation of vinyl sulfides.

Packaging

10 g in glass bottle

Application

Bis(phenylthio)methane (PhSCH2SPh) may be used in the synthesis of the following:
• dihydroxy thioethers
• [Cu4I4{μ-PhS2CH2SPh}2]n
• [(η5-C5Me5)MCl21-(PhS)2CH2)] (M=Rh, Ir ; C5Me5= pentamethylcyclopentadienyl)
• 6-deoxy-1,2:3,4-di-O-isopropylidene-α-D-galactoheptodialdo-1,5-pyranose diphenyl dithioacetal

General description

Bis(phenylthio)methane (PhSCH2SPh) is a dithioether ligand. It forms coordination complex with silver(I) salts. It participates in the synthesis of (-)-rasfonin.

Price and Availability

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
UN 3335
WGK Germany 
3
Flash Point(F) 
235.4 °F
Flash Point(C) 
113 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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