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480835 Aldrich

2-Bromo-4-methylanisole

97%

Synonym: 3-Bromo-4-methoxytoluene

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Properties

Related Categories Building Blocks, C8, Chemical Synthesis, Ethers, Organic Building Blocks,
InChI Key   DHPUIKWBNXTXOB-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.565(lit.)
bp   124-125 °C/20 mmHg(lit.)
mp   15.5 °C(lit.)
density   1.392 g/mL at 25 °C(lit.)

Description

Packaging

10 g in glass bottle

Application

2-Bromo-4-methylanisole may be used in the synthesis of:
• 1,6-bis(2-hydroxy-5-methylphenyl)pyridine (H2mdppy)
• 1,8-dimethoxy-4-methylanthra-quinone
• ethyl 2-(2-methoxy-5-methylphenyl)-2-methyl-4-oxocyclopentanecarboxylate
It may be used as starting material in the multi-step synthesis of sesquiterpene (±)-herbertenolide.

General description

2-Bromo-4-methylanisole can be prepared via bromination of 4-methylanisole using poly(4-vinylpyridinium bromochromate).

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
235.4 °F
Flash Point(C) 
113 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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