Synonym: (±)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene, (±)-BINAP, [1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine]
|Related Categories||Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Polydentate Phosphine Ligands|
|Buchwald-Hartwig Cross Coupling Reaction|
|C-C Bond Formation|
Ligand employed in a palladium-catalyzed arylamine coupling in the preparation of demethylthiocholchines.1 Used with Cu (II) to catalyze addition of arylsulfonamides to styrenes and olefins.2 Amination of terpyridines with Pd catalysis.3
Racemic version of BINAP.4
5, 25, 100 g in glass bottle
Certificate of Analysis
Certificate of Origin
Sigma-Aldrich offers an extended variety of phosphines utilized in C-C bond forming processes. Recent work reported by Prof. Gregory Fu and coworkers has expanded the utility of trialkylphosphines an...
ChemFiles Volume 4 Article 2
Keywords: C-C bond formation
3. Tetrahedron Lett. 47, 5079, (2006)
4. Organometallics 23, 3398-3416, (2004)
Adv. Synth. Catal. 345, 15-32, (2003)
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Need larger quantities for your development, manufacturing or research applications?