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483494 Aldrich

2,5-Dimethoxyphenylboronic acid

Synonym: 2,5-Dimethoxybenzeneboronic acid

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Description

Other Notes

Contains varying amounts of anhydride

Packaging

5, 25 g in glass bottle

Application

Reactant for:
• Suzuki-Miyaura1,2,3,4 and Negishi couplings4

Price and Availability

Safety & Documentation

Protocols & Articles

Articles

Arylboronic Acids

Aldrich is pleased to present its complete selection of arylboronic acids, the building blocks of the Suzuki coupling experiment. Most arylboronic acids readily undergo dehydration reactions to give ...
Aldrich ChemFiles 2001, 1.1, 5.
Keywords: Building blocks, Coupling reactions, Dehydration reaction, Suzuki coupling

Boronic Acids

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
Aldrich ChemFiles 2007, 7.7, 3.
Keywords: Chemfiles, Coupling reactions, Dehydration reaction, Suzuki coupling

Peer-Reviewed Papers

References

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1. Synthesis of trifluoromethyl-substituted di- and terphenyls by site-selective Suzuki-Miyaura reactions of 1,4-dibromo-2-trifluoromethyl-benzene Ullah, I.; et al. Synlett, 1895-1899, (2011)

2. Synthesis of 1,2-diarylnaphthalenes by chemoselective Suzuki-Miyaura reactions of 2-bromo-1-(trifluoromethanesulfonyloxy)naphthalene Hassan, Z.; et al. Synlett, 1827-1830, (2011)

3. Site-selective Suzuki-Miyaura reactions of 1,4- and 3,5-bis(trifluoromethylsulfonyloxy)-2-naphthoates Ibad, M. F.; et al. Synthesis, 2101-2116, (2011)

4. Suzuki-Miyaura and Negishi approaches to a series of forensically relevant pyridines and pyrimidines Blachut, D.; et al. Synthesis, 3496-3506, (2011)

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