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496065 Aldrich

2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine

98%

Synonym: (R,R)-2,6-Bis(4,5-dihydro-4-phenyl-2-oxazolyl)pyridine, (R,R)-2,6-Bis(4-phenyl-2-oxazolinyl)pyridine

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, PyBOX More...
InChI Key   HLHBIMJNCKZZQO-SFTDATJTSA-N
assay   98%
optical activity   [α]22/D 187°, c = 1 in methylene chloride
mp   171-175 °C(lit.)

Description

Packaging

2 g in glass bottle

500 mg in glass insert

Application

2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine [Pybox] may be used as a chiral ligand in the copper-catalyzed enatioselective arylation of N-arylated tetrahydroisoquinolines (THIQs) with arylboronic acids in the presence of a photoredox catalyst.

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Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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