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499994 Aldrich

3,4-(Methylenedioxy)phenylboronic acid

Synonym: 1,3-Benzodioxole-5-boronic acid

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Properties

Related Categories Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids,
InChI Key   CMHPUBKZZPSUIQ-UHFFFAOYSA-N
mp   224-229 °C(lit.)

Description

Other Notes

Contains varying amounts of anhydride

Packaging

1, 5 g in glass bottle

Application

Reactant involved in:
• Petasis reaction between glyoxylic acid, α-amino phosphonates, and organylboronic acids
• Mannich-type multicomponent assembly and 1,3-dipolar cycloaddition for synthesis of tetrahydroisoquinoline fused isoxazolidine scafford
• Suzuki-Miyaura cross-coupling of aryl and heteroaryl halides
• Oxidative Heck reaction for synthesis of functionalized cinnamaldehyde derivatives
• Intramolecular Alder-ene and Pictet-Spengler reactions for synthesis of crinine

Price and Availability


KitAlysis - Increasing Catalysis Productivity

Cross-Coupling Guide
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Arylboronic Acids

Aldrich is pleased to present its complete selection of arylboronic acids, the building blocks of the Suzuki coupling experiment. Most arylboronic acids readily undergo dehydration reactions to give ...
Aldrich ChemFiles 2001, 1.1, 5.
Keywords: Building blocks, Coupling reactions, Dehydration reaction, Suzuki coupling

Boronic Acids - Aldrich ChemFiles 2007, 7.7, 3.

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
Aldrich ChemFiles 2007, 7.7, 3.
Keywords: Chemfiles, Coupling reactions, Dehydration reaction, Suzuki coupling

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