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52435 Aldrich

cis-1,4-Hexadiene

≥99.0%

  • CAS Number 7318-67-4

  • Empirical Formula (Hill Notation) C6H10

  • Molecular Weight 82.14

  •  Beilstein Registry Number 1839519

  •  EC Number 230-783-6

  •  MDL number MFCD00066517

  •  PubChem Substance ID 24874405

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Properties

Related Categories Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks More...
InChI Key   PRBHEGAFLDMLAL-XQRVVYSFSA-N
assay   ≥99.0%
refractive index   n20/D 1.415
bp   65-66 °C(lit.)
density   0.707 g/mL at 20 °C(lit.)

Description

Packaging

5 mL in glass bottle

General description

cis-1,4-Hexadiene can be synthesized from the cobalt-catalyzed reaction between butadiene and ethylene. The reaction of this hydrocarbon with Fe(CO)5 affords the trans-1,3-hexadiene-iron tricarbonyl complex (I), plus a small amount of the trans,trans-2,4-hexadiene complex(II). Mechanism of the conversion of cis-1,4-hexadiene to trans-2-methyl-1,3-pentadiene, via rearrangement in the presence of a nickel catalyst has been investigated.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2458 3 / PGII
WGK Germany 
3
RTECS 
MM1997000
Flash Point(F) 
-50.8 °F
Flash Point(C) 
-46 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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