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528951 Aldrich

Methyl 2-fluorobenzoate

97%

  • CAS Number 394-35-4

  • Linear Formula FC6H4CO2CH3

  • Molecular Weight 154.14

  •  Beilstein Registry Number 1862493

  •  EC Number 206-894-0

  •  MDL number MFCD00017913

  •  PubChem Substance ID 24877631

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Properties

Related Categories Aryl Fluorinated Building Blocks, Building Blocks, C7-C8, C8 to C9, Carbonyl Compounds,
InChI Key   QAFJIJWLEBLXHH-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.502(lit.)
bp   109-110 °C/35 mmHg(lit.)
density   1.21 g/mL at 25 °C(lit.)

Description

Packaging

5 g in glass bottle

Application

Methyl 2-fluorobenzoate may be used to synthesize 2-fluoro-α-methylstyrene and 2-fluorophenyldiphenylmethanol.

General description

Methyl 2-fluorobenzoate is an ortho-halogen-substituted methyl benzoate ester. It reacts with hydrazide to afford 2-fluorobenzoic hydrazide. Methyl 2-fluorobenzoate undergoes enzymatic dihydroxylation via the whole-cell fermentation in the presence of Escherichia coli JM109 (pDTG601A) to afford a diol.

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Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
199.4 °F
Flash Point(C) 
93 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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