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541443 Aldrich

MEH-PPV

average Mn 40,000-70,000

Synonym: MEH-PPV, Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]

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Properties

Related Categories Donor Materials, Light-Emitting Polymers (LEPs), Materials Science, OLED and PLED Materials, Organic Field Effect Transistor (OFET) Materials,
mol wt   average Mn 40,000-70,000
fluorescence   λex 493 nm; λem 554 nm in toluene
Orbital energy   HOMO 5.3 eV 
  LUMO 3 eV 
OLED Device Performance   ITO/PEDOT:PSS/MEH-PPV/Al
• Color: orange-red
• Max. Luminance: 220 Cd/m2
• Max. EQE: 0.3 %
• Turn-On Voltage: 3.8 V
  ITO/PEDOT:PSS/MEH-PPV/PBO/Al
• Color: orange-red
• Max. Luminance: 970 Cd/m2
• Max. EQE: 1.9 %
• Turn-On Voltage: 2.9 V
  ITO/PEDOT:PSS/MEH-PPV/PBZT/Al
• Color: orange-red
• Max. Luminance: 1400 Cd/m2
• Max. EQE: 2.5 %
• Turn-On Voltage: 2.8 V
OPV Device Performance   ITO/MEH-PPV/BBL/Al
• Short-circuit current density (Jsc): 1.98 mA/cm2
• Open-circuit voltage (Voc): 0.93 V
• Fill Factor (FF): 0.47
• Power Conversion Efficiency (PCE): 1.1 %
  ITO/MEH-PPV:PC61BM(1:4)/Ca
• Short-circuit current density (Jsc): 2 mA/cm2
• Open-circuit voltage (Voc): 0.8 V
• Fill Factor (FF): 0.25
• Power Conversion Efficiency (PCE): 1.5 %
Mw/Mn   ~6
storage temp.   2-8°C

Description

Frequently Asked Questions

Frequently Asked Questions are available for this Product.

Application

Useful in producing bright and efficient white polymeric light emitting diodes.

Conducting polymer in solar cells and carbon nanotube OLEDs. Useful in producing bright and efficient white polymeric light emitting diodes.
Filter before application.

General description

Light-emitting conjugated polymer.

Packaging

1 g in glass bottle

250 mg in glass insert

Protocols & Applications

Organic Semiconductor Laser Materials

Price and Availability

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Frequently Asked Questions

Which document(s) contains shelf-life or expiration date information for a given product?
If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis. These documents are located on the product detail page under Useful Links & Tools. Click on the following link to search for a Certificate of Analysis. Please click the following link to see the details on our Product Dating Information.
How do I get lot-specific information or a Certificate of Analysis?
A Certificate of Analysis is available by lot number and can be obtained through our Advanced Search Option: http://www.sigmaaldrich.com/catalog/AdvancedSearchPage.do
How do I find price and availability?
There are several ways to find pricing and availability for our products.  Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers. 
What is the Department of Transportation shipping information for this product?
Transportation information can be found in Section 14 of the product's (M)SDS. To access the shipping information for this material, use the link on the product detail page for the product, or search here. 
What is the solubility of Product 541443, Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]?
Per our quality control testing, this product is soluble in toluene with heat and sonication at a concentration of 0.02 g/L.
What is the glass transition temperature (Tg) of Product 541443, Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]?
Unfortunately, the glass transition temperature (Tg) is not determined for this product.
Can Product 541443, Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene], efficiently convert light to electricity?
The polyphenylenevinylene (PPV) polymers themselves do not convert light to electricity very efficiently.  They need to be blended with an electron transport material. The best material for this is a fullerene material called [6,6]-Phenyl C61 butyric acid methyl ester (PCBM, offered as #684430, 684449, 684457). There are several references that discuss polymer-fullerene heterojunctions.  One paper on this subject is Brabec, C.J.; et. al. Applied Physics Letters, 80, 1288 (2002).
Does Product 541443, Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene], contain a dopant?
This product does not contain a dopant.
My question is not addressed here, how can I contact Technical Service for assistance?
Use the option to the right to "Ask a Question" by email of a Technical Service Scientist.
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Protocols & Articles

Articles

Functionalized Fullerenes: Nanomaterials for Organic Electronics

Fullerenes, the older nanomaterial relatives of carbon nanotubes, continue to stimulate advances in applied and fundamental science. Fullerenes are excellent electron acceptors and can be chemically ...
Material Matters 2007, 2.1, 18.
Keywords: Electronics, Help, Material Matters, Nanotubes, Organic electronics, Semiconductor, Solvents, Type

High-Performance Semiconductor Polymers Based on Diketopyrrolopyrrole and Thienothiophene

Tony Wigglesworth, Yiliang Wu, Cuong Vong and Matthew Heuft Xerox Research Centre of Canada, Mississauga ON, L5K 2L1 Email: tony.wigglesworth@xrcc.xeroxlabs.com
Keywords: Electronics, Nucleic acid annealing, Printed electronics, Semiconductor, Solar cells, Solvents

Light-Emitting Polymers

Conjugated polymers with long range p-electron delocalization behave as processable organic “metals” in their doped state and as semiconducting materials in their neutral undoped state.1–3 Many undop...
Prof. Qibing Pei
Material Matters 2007, 2.3, 26.
Keywords: Absorption, Alkylations, Applications, Bacterial conjugations, Catalysis, Condensations, Environmental, Grignard Reaction, Infrared spectroscopy, Materials Science, Phase transitions, Polymerization reactions, Radical polymerization, Semiconductor, Solar cells, Solvents, Spectra, Suzuki coupling, Suzuki reactions, Type

Organic Semiconductor Laser Materials

Over recent years, a wide variety of challenges aiming for electrical pumping of organic laser diodes have been addressed. However, organic laser diodes have difficulty gaining widespread application...
Chihaya Adachi, Hajime Nakanotani
Material Matters 2009, 4.3, 74.
Keywords: Absorption, Amplification, Electronics, Infrared spectroscopy, Nitrogen phosphorus detector, Organic electronics, Recombination, Semiconductor, Spectra, Type

PCBM-Based n-Type Semiconductors

Unique chemistry and physics of fullerene (C60) materials continue to stimulate advances in applied and fundamental science. Fullerenes are known as excellent electron acceptors and can be chemically...
Keywords: Absorption, Diffusion, Electronics, Organic electronics, Photosynthesis, Reductions, Semiconductor, Solar cells, Solvents

Synthesis of Mesoporous Materials

Mespoporous materials, also known as mesoporous molecular sieves, are a class of 3D-nanostructures with well-defined mesoscale (2–50 nm diameter) pores and surface areas up to 1000 m2/g.1 In terms of...
Material Matters 2008, 3.1, 17.
Keywords: Absorption, Applications, Catalog, Catalysis, Condensations, Diffusion, Material Matters, Methods, Sol-gel

Peer-Reviewed Papers
15

References

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