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543039 Aldrich

(R)-1,4-Dioxaspiro[4.5]decane-2-carboxaldehyde

Synonym: (R)-2,3-Cyclohexylideneglyceraldehyde, (R)-Cyclohexylideneglyceraldehyde, 2,3-O-Cyclohexylidene-D-glyceraldehyde, O,O-Cyclohexylidene-(R)-glyceraldehyde

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Properties

Related Categories Aldehydes, Asymmetric Synthesis, Building Blocks, C9, Carbonyl Compounds,
InChI Key   FFGZPNNLXMQFMO-QMMMGPOBSA-N
optical activity   [α]/D 60±10° in chloroform
refractive index   n20/D 1.472(lit.)
density   1.108 g/mL at 25 °C(lit.)

Description

Application

Used as a building block.

Reactant for:
• Proline-catalyzed Diels Alder reaction
• Stereodivergent synthesis of carbahexofuranoses employing a Wittig olefination-Claisen rearrangement protocol
• Wittig reactions
• Crotylation reactions
• Asymmetric synthesis of Goniothalesdiol A via stereocontrolled allylation and base-catalyzed oxy-Michael addition

Other Notes

Contains varying amounts of polymer

Packaging

1 g in glass bottle

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles
Peer-Reviewed Papers
15

References

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