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558958 Aldrich

4-Chlorobenzyl bromide

97%

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Properties

Related Categories Aryl, Building Blocks, C7, Chemical Synthesis, Halogenated Hydrocarbons,
InChI Key   KQNBRMUBPRGXSL-UHFFFAOYSA-N
assay   97%
mp   48-52 °C(lit.)

Description

Packaging

25, 100 g in glass bottle

4-Chlorobenzyl bromide may be used to synthesize:
• 1-[1-[2-[(4-chlorobenzyl)thio]phenyl]vinyl]-1H-imidazole
• 6-[4-(4-chlorobenzyl)piperazinyl]chromane
• N,N′-bis(4-chlorobenzyl)piperazine
• N-(4-chlorobenzyl)piperazine

General description

4-Chlorobenzyl bromide undergoes carbonylation in the presence of dimer of chloro(1,5-cyclooctadiene)rhodium(I) to yield the corresponding phenylacetic acid. It can be synthesized by reacting 4-chlorobenzyl alcohol with bromodimethylsulfonium bromide (BDMS) It can also be synthesized by refluxing a mixture of 4-chlorobenzaldehyde, chlorotrimethylsilane, 1,1,3,3-tetramethyldisiloxane and lithium bromide.

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Laboratory Gloves
Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1759 8 / PGII
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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