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559148 Aldrich

Ethyl (2-methylbenzoyl)acetate

97%

Synonym: Ethyl 2-(2-methylbenzoyl)acetate, Ethyl 3-(2-methylphenyl)-3-oxopropanoate, Ethyl 3-oxo-3-(o-tolyl)propanoate, Ethyl o-methylbenzoylacetate, Ethyl o-toluoylacetate

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Properties

Related Categories Building Blocks, C12 to C63, Carbonyl Compounds, Chemical Synthesis, Esters,
InChI Key   UNULPFKXRJPSCO-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.5255(lit.)
bp   256-257 °C(lit.)
density   1.069 g/mL at 25 °C(lit.)

Description

Packaging

1 g in glass bottle

Application

Reactant for:
• Preparation of highly substituted furans by tandem condensation-cyclization reactions using bismuth triflate catalyst
• Co/Mn-mediated oxidative cross-coupling
• Enantioselective ruthenium-catalyzed hydrogenation
• Preparation of cambinol analogs for sirtuin inhibition with antitumor action

General description

Ethyl (2-methylbenzoyl)acetate is a β-keto ester. It undergoes Co/Mn mediated oxidative coupling reaction with various indole derivatives.

Price and Availability

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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