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567159 Aldrich

1,1′-Bis(phenylphosphinidene)ferrocene

97%

Synonym: 1,1′-(Ferrocenediyl)phenylphosphine

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
InChI Key   HKOUDNXXOXEYNZ-UHFFFAOYSA-N
assay   97%
mp   88-92 °C(lit.)
storage temp.   2-8°C

Description

Packaging

1 g in glass bottle

Application

Reactant for:
• Preparation of macrocyclic tridentate ferrocenylphosphine ligands
• Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations
• Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes
• Ring-opening reactions via ring slippage
• Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate

Price and Availability

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Protocols & Articles
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