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570214 Aldrich

trans-2-Phenylvinylboronic acid pinacol ester

Synonym: (E)-4,4,5,5-Tetramethyl-2-(2-phenylvinyl)-1,3,2-dioxaborolane, (E)-4,4,5,5-Tetramethyl-2-styryl-1,3,2-dioxaborolane, 4,4,5,5-Tetramethyl-2-((E)-2-phenylethenyl)-1,3,2-dioxaborolane, trans-2-Styreneboronic acid pinacol ester, trans-2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)styrene

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Properties

Related Categories Alkenyl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents More...
InChI Key   ARAINKADEARZLZ-ZHACJKMWSA-N
mp   27-33 °C(lit.)

Description

Packaging

1 g in glass bottle

Application

Reactant for:
• Oxidative coupling reactions catalyzed by areneruthenium
• Cycloaddition reactions
• Preparation of allyl vinyl ethers via Cu-catalyzed coupling with alcohols
• Preparation of 5-vinyl-3-pyridinecarbonitriles as PKCθ inhibitors
• Diastereoselective addition to zincated hydrazones and stereospecific trapping of boron/zinc bimetallic intermediates by carbon electrophiles
• Regioselective and stereoselective Pd-catalyzed chelate-controlled intermolecular oxidative Heck reactions

Price and Availability


KitAlysis - Increasing Catalysis Productivity

Cross-Coupling Guide
Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
>230 °F
Flash Point(C) 
>110 °C
Protocols & Articles

Articles

Boronic Acid Esters - Chemfiles Volume 4 Article 2

The synthesis of biaryl compounds via the Suzuki–Miyaura coupling reaction has become more commonplace now that many arylboronic acids are readily available. Several years ago, Miyaura et al. demonst...
Chemfiles Volume 4 Article 2
Keywords: Coupling reactions

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