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571350 Aldrich

1-Phenylvinylboronic acid

95%

Synonym: α-Methylene-α-tolueneboronic acid, α-Phenyl vinylboronic acid, (1-Phenylethenyl)boronic acid, Styrene α-boronic acid

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Properties

Related Categories Alkenyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents More...
InChI Key   YJCPVMYUISTDKG-UHFFFAOYSA-N
assay   95%
mp   125 °C (dec.)(lit.)
storage temp.   2-8°C

Description

Other Notes

Contains varying amounts of anhydride

Packaging

1, 5 g in glass bottle

Application

Reactant involved in:
• Halogenation of alkynes for preparation of enol esters
• Liebeskind-Srogl cross-coupling
• Homocoupling of arylboronic acids for synthesis of biaryls
• Iterative cross-coupling of boronate building blocks
• Enantioselective hydrogenation of hydroxyphenyl styrenes
• Samarium diiodide-mediated cyclization for synthesis of substituted benzannulated cyclooctanol derivatives
• Suzuki-Miyaura cross-coupling for synthesis of C-6-substituted uridine phosphonates

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Boronic Acids

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
Aldrich ChemFiles 2007, 7.7, 3.
Keywords: Chemfiles, Coupling reactions, Dehydration reaction, Suzuki coupling

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