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647640 Aldrich

Zirconium(IV) chloride

anhydrous, powder, 99.99% trace metals basis

Synonym: Tetrachlorozirconium, Zirconium tetrachloride

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Essential Chemicals, Materials Science,
grade   anhydrous
vapor pressure   1 mmHg ( 190 °C)
assay   99.99% trace metals basis
form   powder
impurities   <50 ppm hafnium
transition temp   sublimation point 331 °C
density   2.8 g/mL at 25 °C(lit.)

Description

Packaging

5, 25 g in ampule

Price and Availability

Suggested Laboratory Gloves


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Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Corrosive to the respiratory tract., Reacts violently with water.
Hazard Codes (Europe) 
C
Risk Statements (Europe) 
Safety Statements (Europe) 
26-36/37/39-45
RIDADR 
UN 2503 8 / PGIII
WGK Germany 
3
RTECS 
ZH7175000

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Articles

High Purity Inorganics

Aldrich-APL (AAPL) offers a complete line of the highest purity inorganic salts and materials for the micro and nanoelectronics market. Through proprietary processes, AAPL manufactures metal halide s...
Chemfiles Volume 4 Article 3
Keywords: Catalog, Inductively coupled plasma, Mass spectrometry, Nanoelectronics, Sublimation

Peer-Reviewed Papers

References

Set your institution to view full text papers.

Hydroaminations of unactivated alkenes with basic alkylamines: group 4 metal halide catalysts and Brønsted-acid organocatalysts. Ackermann L, Kaspar LT, and Althammer A Org. Biomol. Chem. 5(12), 1975-8, (2007)

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Direct amide coupling of non-activated carboxylic acids and amines catalysed by zirconium(IV) chloride. Lundberg H, Tinnis F, and Adolfsson H Chemistry 18(13), 3822-6, (2012)

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Efficient transamidation of primary carboxamides by in situ activation with N,N-dialkylformamide dimethyl acetals. Dineen TA, Zajac MA, and Myers AG J. Am. Chem. Soc. 128(50), 16406-9, (2006)

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Awakening a dormant catalyst: salicylaldimine systems for ethene/tert-butylstyrene copolymerization. Theaker GW, Morton C, and Scott P Dalton Trans. (48), 6883-5, (2008)

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Microwave-assisted synthesis of substituted tetrahydropyrans catalyzed by ZrCl4 and its application in the asymmetric synthesis of exo- and endo-brevicomin. Singh S and Guiry PJ J. Org. Chem. 74(15), 5758-61, (2009)

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Hyperphosphataemia in renal failure: causes, consequences and current management. Albaaj F and Hutchison A Drugs 63(6), 577-96, (2003)

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Direct cyclopropanation of 1-alkynylphosphonates by Cp2ZrCl2/2EtMgBr/2AlCl3 to afford cyclopropylmethylphosphonates. Aziz Quntar AA and Srebnik M J. Org. Chem. 71(2), 730-3, (2006)

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Ordered, mesoporous metal phosphonate materials with microporous crystalline walls for selective separation techniques. Ma TY, Li H, Tang AN, et al. Small 7(13), 1827-37, (2011)

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Application of high-surface-area ZrO2 in preconcentration and determination of 18 elements by on-line flow injection with inductively coupled plasma atomic emission spectrometry. Vassileva E and Furuta N Fresenius J. Anal. Chem. 370(1), 52-9, (2001)

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Fluorinated β-nitro amines by a selective ZrCl4-catalyzed aza-Henry reaction of (E)-trifluoromethyl aldimines. Fioravanti S, Pellacani L, and Vergari MC Org. Biomol. Chem. 10(41), 8207-10, (2012)

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An efficient one-pot synthesis of benzothiazolo-4?-anilino-podophyllotoxin congeners: DNA topoisomerase-II inhibition and anticancer activity. Ahmed Kamal et al Bioorg. Med. Chem. Lett. 21, 350-3, (2011)

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Ultrasound promoted ZrCl(4) catalyzed rapid synthesis of substituted 1,2,3,4-tetrahydropyrimidine-2-ones in solvent or dry media. Kumar H and Parmar A Ultrason. Sonochem. 15(2), 129-32, (2008)

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Lipid bilayer templated gold nanoparticles nanoring formation using zirconium ion coordination chemistry. Xiao X, Montaño GA, Allen A, et al. Langmuir 27(15), 9484-9, (2011)

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Polymer complexes XXXVII novel models and structural of symmetrical poly-Schiff base on heterobinuclear complexes of dioxouranium(VI). El-Sonbati AZ, El-Bindary AA, and Rashed IG Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 58(7), 1411-24, (2002)

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Preparation and characterization of films based on zirconium sulfophenyl phosphonate and chitosan. Yang Y, Liu C, Wu H, et al. Carbohydr. Res. 345(1), 148-53, (2010)

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A study on the conversion of indanones into carbostyrils. Torisawa Y, Nishi T, and Minamikawa Ji Bioorg. Med. Chem. 11(10), 2205-9, (2003)

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Influence of nanopores of MCM-41 and SBA-15 confining (n-BuCp)2ZrCl2 on copolymerization of ethylene-alpha-olefin. Y. S. Ko, et al., J. Nanosci. Nanotechnol. 10, 180-185, (2010)

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Effects of lacquer polysaccharides, glycoproteins and isoenzymes on the activity of free and immobilised laccase from Rhus vernicifera. Wan YY, Lu R, Akiyama K, et al. Int. J. Biol. Macromol. 47(1), 76-81, (2010)

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Fabrication and characterization of poly(DL-lactic-co-glycolic acid)/zirconia-hybridized amorphous calcium phosphate composites. Whited BM, Goldstein AS, Skrtic D, et al. J. Biomater. Sci. Polym. Ed. 17(4), 403-18, (2006)

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Layer-by-layer assembly of ordinary and composite coordination multilayers. Doron-Mor I, Cohen H, Cohen SR, et al. Langmuir 20(24), 10727-33, (2004)

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Merck 14,10174

Fieser 1,1295

Corp MSDS 1 (2), 3634:A / RegBook 1 (3), 3333:B / Sax 6, 2758

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