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656763 Aldrich

Di-μ-chlorotetraethylene dirhodium(I)

Synonym: Bis[chlorobis(ethylene)rhodium], Bis[chlorodiethylenerhodium], Chlorobis(ethylene)rhodium dimer, Dichlorotetra(ethene)dirhodium, Dichlorotetrakis(ethene)dirhodium, Diethylenerhodium chloride dimer, Divinylrhodium chloride dimer, Tetrakis(ethylene)dichlorodirhodium, [Rh(C2H4)2Cl]2

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium More...
InChI Key   OOQJCPOXJFCGCR-UHFFFAOYSA-L
storage temp.   −20°C

Description

Application

Precursor to Rh(I) norbornadiene catalyst used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones.

Packaging

1 g in glass bottle

100 mg in glass bottle

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Asymmetric Conjugate Addition

In the past 5 years, chiral diene ligands have surfaced for a variety of asymmetric transformations. Hayashi1 and Carreira2 pioneered this field by synthesizing chiral diene ligands that formed stabl...
William Sommer
Aldrich ChemFiles 2008, 8.6, 11.
Keywords: Addition reactions, Arylations, Asymmetric synthesis, Building blocks, Catalysis, Chemfiles, Ligands, Type

Asymmetric Hydrosilylation

The asymmetric hydrosilylation of olefins has proven to be a useful method to access a variety of chiral alcohols.1 The introduction of the silica moiety allows further transformation of the molecule...
William Sommer
Aldrich ChemFiles 2008, 8.6, 4.
Keywords: Asymmetric synthesis, Chemfiles, Hydrosilylations, Ligands, transformation

Carreira DOLEFIN Ligands

For the past years, the Carreira group has been employing chiral [2.2.2]bicyclooctadienes derived from (R)- or (S)-carvone in Ir(I)-catalyzed kinetic resolution of allylic carbonates1 and Rh(I)-catal...
Aldrich ChemFiles 2006, 6.10, 4.
Keywords: Addition reactions, Asymmetric synthesis, Catalysis, Chemfiles, Infrared spectroscopy, Ligands, Methods

Palladium-Catalyzed Reduction of Allylic Esters

The palladium catalyzed reduction of allylic esters provides a convenient method to access chiral olefins.1Hayashi et al. studied the activity of the MOP ligand with palladium toward the reduction of...
William Sommer
Aldrich ChemFiles 2008, 8.6, 4.
Keywords: Catalysis, Chemfiles, Ligands, Reductions

Peer-Reviewed Papers
15

References

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06693 Timestrip Plus -20 °C

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