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660140 Aldrich

NaK Silica gel (K2Na) Stage I

extent of labeling: ~35 wt. % Na-K loading

Synonym: K2Na-SG-I, Sodium-potassium alloy on silica gel (K2Na)

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Properties

Related Categories Alkali Metals, Chemical Synthesis, Reduction, Synthetic Reagents
InChI Key   BITYAPCSNKJESK-UHFFFAOYSA-N
extent of labeling   ~35 wt. % Na-K loading

Description

Frequently Asked Questions

Frequently Asked Questions are available for this Product.

Packaging

5, 25 g in glass bottle

Application

Alkali Metal Silica Gels from SiGNa

Alternative to other reagents for desulfurizations, dehalogenations(as Wurtz coupling reactions), and Birch reductions.

Additionally can be used as:
• A reducing agent for aliphatic ester substrates
• A deprotectant in place of the typical heavy metal deprotectant

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN 3404 4.3 / PGI
WGK Germany 
1
Protocols & Articles

Articles

Alkali Metal Silica Gels from SiGNa

Alkali metals have long been used in synthetic chemistry as reducing agents, but their pyrophoric nature has often prevented their use in larger-scale reactions. Alkali metals react violently with wa...
Keywords: Birch Reduction, Bouveault-Blanc Reduction, Green chemistry, Reductions, transformation

Alkali Silica Gels

Alkali metals have long been used in synthetic chemistry as reducing agents, but their pyrophoric nature has often prevented their use in larger-scale reactions. Alkali metals react violently with wa...
ChemFiles Volume 5 Article 9
Keywords: Applications, Birch Reduction, Coupling reactions, Reductions, Solvents, Wurtz reaction

Related Content

Alkali Metal Silica Gels from SiGNa: Powerful Reducing Agents

Alkali metals have long been used in synthetic chemistry as reducing agents, but their pyrophoric nature has often prevented their use in larger-scale reactions. Alkali metals react violently with wa...
Keywords: Applications, Birch Reduction, Bouveault-Blanc Reduction, Green chemistry, Reductions, Solvents, transformation

Peer-Reviewed Papers
15

References

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