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661058 Aldrich

Methoxy(cyclooctadiene)rhodium(I) dimer

Synonym: [Rh(OMe)(1,5-cod)]2

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium More...
InChI Key   BDQMDBOKWREKIT-MIXQCLKLSA-N
mp   192-225 °C

Description

Application

Precursor for organorhodium(I) species, catalyst for cascade1,4-addition-aldol reaction, 1,4-addition of alcohols, and hydroformylation

Rhodium catalyst employed in the cyclization of cyano-substituted unsaturated esters in the presence of aryl 9-BBN leading to 5- and 6-membered β-enamino esters.

Efficient and Selective Catalysts for Asymmetric Synthesis

Packaging

1 g in glass bottle

250 mg in glass bottle

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

[RhOH((S)-BINAP)]2 (1), [RhOMe((S)-BINAP)]2 (2), and Catalyst Precursors

In the late 1990s, the Hayashi group successively developed rhodium-based catalysts applied in the asymmetric, conjugate addition of arylboronic acids to C=C bonds.1 They utilized Rh-BINAP catalysts ...
ChemFiles Volume 5 Article 10
Keywords: Addition reactions, Asymmetric synthesis, Catalysis, Natural product synthesis, Rearrangements, Reductions, Solvents, transformation

Related Content

Hayashi Catalysts in Chemical Synthesis

The Hayashi group at Kyoto University has spearheaded the development of rhodium-based catalysts applied in the asymmetric, conjugate addition of arylboronic acids to C=C bonds.1 They utilized Rh-BIN...
Keywords: Addition reactions, Asymmetric synthesis, Building blocks, Catalysis, Eliminations

Peer-Reviewed Papers
15

References

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