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662283 Aldrich

Bis(tert-butylcarbonyloxy)iodobenzene

97%

Synonym: (Di-tert-butylcarbonyloxyiodo)benzol, 2,2-Dimethylpropanoic acid, phenyliodine complex, Bis(2,2-dimethylpropanoato-O)phenyliodide, Di-(Pivaloyloxy)iodobenzene

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Properties

Related Categories C-H Activation, Catalysis and Inorganic Chemistry, Chemical Synthesis, Hypervalent Iodine, Oxidants,
InChI Key   DZKPLZUSZXYHFB-UHFFFAOYSA-N
assay   97%
mp   104-109 °C

Description

Application

Hypervalent iodine reagent used with the Rh2(esp)2 catalyst (662623) in the amination of C-H bonds.

Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination

Reagent for:
• Preparation of α,β-unsaturated-γ-lactams via Rh-catalyzed C-H amination of allene carbamates, then Ru-catalyzed cyclocarbonylation
• Palladium-catalyzed diamination
• Preparation of functionalized bicyclic heterocyclic compounds by rhodium-catalyzed allene amidation and cyclization
• Preparation of piperidine and pyrrolidine derivatives via copper-catalyzed intramolecular aminoacetoxylation of aminoolefins
• C-H acyloxylation of arenes

• Hypervalent iodine oxidant

Packaging

5, 25 g in glass bottle

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Rh2(esp)2 (7): An Exceptionally Efficient and Selective Catalyst for C–H Amination

By substituting tetramethylated m-benzenediproprionic acid 1 via a decarboxylative metathesis of Rh2(OAc)4 (Scheme 9), the Du Bois group at Stanford has improved the catalytic performance of Rh with ...
ChemFiles Volume 5 Article 10
Keywords: Aminations, Asymmetric synthesis, Catalysis, Cyclizations, Metathesis, Methods, Poisons, Solvents

Related Content

Rh2(esp)2 Catalyst

By substituting tetramethylated m-benzenediproprionic acid 1 via a decarboxylative metathesis of Rh2(OAc)4 (Scheme 1), the Du Bois group at Stanford has improved the catalytic performance of Rh with ...
Keywords: Aminations, Asymmetric synthesis, Catalysis, Cyclizations, Metathesis, Methods, Poisons, Solvents

Peer-Reviewed Papers
15

References

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