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662623 Aldrich

Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)]

96%

Synonym: Rh2(esp)2

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Properties

Related Categories C-H Activation, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Rhodium More...
InChI Key   OBMUTUNJWNQIAJ-UHFFFAOYSA-N
assay   96%
mp   >300 °C

Description

Application

Catalyst for an efficient intermolecular amination of tertiary, benzylic C-H bonds.

Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination

Packaging

100, 500 mg in glass bottle

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Allenylboronic Acid Pinacol Ester

The allenylboronate platform has recently been demonstrated to undergo multicomponent reactions in a completely regio- and stereoselective fashion.1 Yoshida and co-workers successfully utilized this ...
Aldrich ChemFiles 2007, 7.1, 6.
Keywords: Anti-depressants, Anti-inflammatory agents, Building blocks, Chemfiles

Rh2(esp)2 (7): An Exceptionally Efficient and Selective Catalyst for C–H Amination

By substituting tetramethylated m-benzenediproprionic acid 1 via a decarboxylative metathesis of Rh2(OAc)4 (Scheme 9), the Du Bois group at Stanford has improved the catalytic performance of Rh with ...
ChemFiles Volume 5 Article 10
Keywords: Aminations, Asymmetric synthesis, Catalysis, Cyclizations, Metathesis, Methods, Poisons, Solvents

Related Content

Rh2(esp)2 Catalyst

By substituting tetramethylated m-benzenediproprionic acid 1 via a decarboxylative metathesis of Rh2(OAc)4 (Scheme 1), the Du Bois group at Stanford has improved the catalytic performance of Rh with ...
Keywords: Aminations, Asymmetric synthesis, Catalysis, Cyclizations, Metathesis, Methods, Poisons, Solvents

Peer-Reviewed Papers
15

References

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