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666025 Aldrich

13,6-N-Sulfinylacetamidopentacene

97%

Synonym: 16-Acetyl-6,13-dihydro-15-oxide -13,6-(epithioimino)pentacene, NSFAAP, soluble pentacene precursor

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Properties

Related Categories Materials Science, Organic Field Effect Transistor (OFET) Materials, Organic and Printed Electronics, p-Type Organic Semiconductors, p-Type Small Molecules More...
InChI Key   HIABOOSIYBUBKB-XUEDKKMFSA-N
assay   97%
mp   169-190 °C
solubility   THF: soluble
  dioxane: soluble
  methylene chloride: soluble
fluorescence   λex 251 nm; λem 498 nm in chloroform
storage temp.   −20°C

Description

Application

Pentacene precursor highly soluble (>50mg/ml) in apolar solvents (halogenated solvents, THF). Converted to pentacene in thin (e.g. spin-cast) films by heating under N2 atmosphere for 5-15 minutes at 120-200°C. Organic thin-film transistors fabricated by solution processing of this precursor afforded highest mobilities - up to 0.8cm2V-1s-1 - reported for a solution-processed organic semiconductor.

This material is highly soluble in CHCl3, MeOH, THF, PGMEA, and other solvents that are commonly used in microelectronics processing.

Packaging

100, 500 mg in glass insert

Preparation Note

Dried thin films convert to pentacene at 150-200 °C

Protocols & Applications

Fabrication of Organic Field Effect Transistor Device Using a Soluble Pentacene Precursor

Price and Availability

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
3
Protocols & Articles

Articles

Silylethyne-Substituted Pentacenes

Research into the use of organic semiconductors in field-effect transistors (FETs) began in earnest in the mid-1990s,1 after early exciting results from vapor-deposited small molecule semiconductors....
John E. Anthony*
Material Matters 2009, 4.3, 58.
Keywords: Applications, Capabilities, Crystallization, Deposition, Electronics, Electrophoretic display, Evaporation, Organic electronics, Semiconductor, Separation, Solar cells, Substitutions

Peer-Reviewed Papers
15

References

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