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667900 Aldrich

N-Boc-2-indolyldimethylsilanol

95%

Synonym: 2-(hydroxydimethylsilyl)-1,1-dimethylethylindole-1-carboxylic acid ester, N-Boc-indol-2-yldimethylsilanol

  • CAS Number 784161-48-4

  • Linear Formula ((C8H5N)(CO2C(CH3)3))Si(CH3)2(OH)

  • Molecular Weight 291.42

  •  MDL number MFCD08457643

  •  PubChem Substance ID 24884947

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Properties

Related Categories Building Blocks, C13 to C27, Chemical Synthesis, Heterocyclic Building Blocks, Indoles More...
InChI Key   ARJIKJGACIMUOM-UHFFFAOYSA-N
assay   95%
refractive index   n20/D 1.545
storage temp.   2-8°C

Description

Application

A useful silicon nucleophile for Pd-catalyzed cross-coupling.

Reactant for:
Palladium-catalyzed cross-coupling reactions

Packaging

1, 5 g in glass bottle

Protocols & Applications

Cross-Coupling using Organosilanols as Powerful Nucleophiles

Price and Availability

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
>230 °F
Flash Point(C) 
>110 °C
Protocols & Articles

Articles

Organosilanes for Cross-coupling

Over the past several years, Pd-catalyzed cross-coupling of silicon compounds has rapidly gained acceptance as a suitable alternative to more commonly known methods such as: Stille (Sn), Kumada (Mg),...
Aldrich ChemFiles 2006, 6.5, 7.
Keywords: Aldrichimica Acta, Antifungals, Catalysis, Coupling reactions, Cross couplings, Grignard Reaction, Ligands, Metallations, Methods, Protocols, Silylations, Vinylations

Related Content

Organosilanols in Chemical Synthesis

Powerful Nucleophiles for Cross-Coupling Over the past several years, the Pd-catalyzed cross-coupling of silicon compounds (Hiyama coupling) has rapidly gained acceptance as a suitable alternative to...
Keywords: Aldrichimica Acta, Antifungals, Catalysis, Chemfiles, Coupling reactions, Cross couplings, Hiyama Coupling, Hydrosilylations, Ligands, Metallations, Methods, Protocols, Silylations

Peer-Reviewed Papers
15

References

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