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  • 668532 - Di-μ-chlorobis[5-hydroxy-2-[1-(hydroxyimino-κN)ethyl]phenyl-κC]palladium(II) dimer

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668532 Aldrich

Di-μ-chlorobis[5-hydroxy-2-[1-(hydroxyimino-κN)ethyl]phenyl-κC]palladium(II) dimer

98%

Synonym: Di-μ-chloro-bis-[5-hydroxy-2-[1-(hydroxyimino-κN)-ethyl]-phenyl-κC]-palladium(II) dimer, Di-μ-chlorobis[5-hydroxy-2-[1-(hydroxyimino-κN)ethyl]phenyl-κC]dipalladium, Nájera Catalyst II

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Other Palladacycle Coupling Catalysts, Palladium More...
InChI Key   VEJSMXSVBZMTSO-FIOBSCOQSA-L
assay   98%
mp   251-255 °C

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Application

Promotes the vinylation of aryl bromides and chlorides with vinylsiloxanes in the presence of aqueous NaOH.

Price and Availability


Essence of Chemistry

Cross-Coupling Guide
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Nájera Catalysts

Oxime-derived palladacycles 3 and 4 (Figure 2) introduced by Professor Carmen Nájera and co-workers at the Universidad de Alicante (Alicante, Spain) are very efficient phosphine-free precatalysts for...
Aldrich ChemFiles 2007, 7.5, 6.
Keywords: Chemfiles, Coupling reactions, Metallations, Solvents

Palladacycle Coupling Catalysts

Palladacyclic catalysts developed by Bedford’s group are examples of a select group of catalysts capable of affecting a variety of coupling reactions using difficult to activate aryl chlorides at ver...
William Sommer
Aldrich ChemFiles 2007, 7.10, 17.
Keywords: Aminations, Catalysis, Chemfiles, Coupling reactions, Ligands, Protocols, Solvents, Stille coupling, Suzuki coupling

Peer-Reviewed Papers
15

References

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