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  • 668532 - Di-μ-chlorobis[5-hydroxy-2-[1-(hydroxyimino-κN)ethyl]phenyl-κC]palladium(II) dimer

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668532 Aldrich

Di-μ-chlorobis[5-hydroxy-2-[1-(hydroxyimino-κN)ethyl]phenyl-κC]palladium(II) dimer

98%

Synonym: Di-μ-chloro-bis-[5-hydroxy-2-[1-(hydroxyimino-κN)-ethyl]-phenyl-κC]-palladium(II) dimer, Di-μ-chlorobis[5-hydroxy-2-[1-(hydroxyimino-κN)ethyl]phenyl-κC]dipalladium, Nájera Catalyst II

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Other Palladacycle Coupling Catalysts, Palladium More...
InChI Key   VEJSMXSVBZMTSO-FIOBSCOQSA-L
assay   98%
mp   251-255 °C

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Application

Promotes the vinylation of aryl bromides and chlorides with vinylsiloxanes in the presence of aqueous NaOH.

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Nájera Catalysts

Oxime-derived palladacycles 3 and 4 (Figure 2) introduced by Professor Carmen Nájera and co-workers at the Universidad de Alicante (Alicante, Spain) are very efficient phosphine-free precatalysts for...
Aldrich ChemFiles 2007, 7.5, 6.
Keywords: Chemfiles, Coupling reactions, Metallations, Solvents

Palladacycle Coupling Catalysts

Palladacyclic catalysts developed by Bedford’s group are examples of a select group of catalysts capable of affecting a variety of coupling reactions using difficult to activate aryl chlorides at ver...
William Sommer
Aldrich ChemFiles 2007, 7.10, 17.
Keywords: Aminations, Catalysis, Chemfiles, Coupling reactions, Ligands, Protocols, Solvents, Stille coupling, Suzuki coupling

Peer-Reviewed Papers
15

References

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