|Related Categories||Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, MacMillan Imidazolidinone OrganoCatalysts|
Highly selective organocatalyst for the Diels-Alder reaction with simple α,β−unsaturated ketones.1
1 g in glass bottle
100, 250, 500 mg in glass bottle
U.S. Pat. 6,369,243 and related patents apply. For research purposes only.
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Certificate of Analysis
|Precautionary statements||P261-P301 + P310-P305 + P351 + P338|
|Personal Protective Equipment||Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges|
|Hazard Codes (Europe)||T|
|Risk Statements (Europe)||25-36/37/38|
|Safety Statements (Europe)||26-36-45|
|RIDADR||UN 2810 6.1 / PGIII|
MacMillan and co-workers have created chiral imidazolidinone organocatalysts that function as the linchpin in a variety of directed enantioselective organic reactions including Diels–Alder and 1,3-di...
Aldrich ChemFiles 2006, 6.7, 11.
Keywords: Addition reactions, Alkylations, Asymmetric synthesis, Chlorinations, Cycloadditions, Epoxidations, Fluorinations, Hydrogenations, Organocatalysis
Developed by Professor David MacMillan at Caltech, imidazolidinone-based OrganoCatalysts™ are designed to serve as general catalysts for a variety of asymmetric transformations. The first highly enan...
Keywords: Alkylations, Asymmetric catalysis, Asymmetric synthesis, Catalysis, Chlorinations, Condensations, Cycloadditions, Diels-Alder reaction, Fluorinations, Friedel-Crafts Alkylation
1. Burk, M. J. et al J. Am. Chem. Soc. 118, 5142, (1996)
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