• USA Home
  • 669393 - N-Methyl-O-benzoylhydroxylamine hydrochloride

EMAIL THIS PAGE TO A FRIEND
669393 Aldrich

N-Methyl-O-benzoylhydroxylamine hydrochloride

97%

Synonym: Benzoic acid N-hydroxymethylamine ester hydrochloride

  • CAS Number 27130-46-7

  • Linear Formula (C6H5)CO2(NHCH3) HCl

  • Molecular Weight 187.62

  •  PubChem Substance ID 24885043

Purchase

Properties

Related Categories C-X Bond Formation (Non-Halogen), Chemical Synthesis, Other Non-Halogen Reagents for C-X Bond Formation, Synthetic Reagents
InChI Key   FTCDQNQIGUCFSA-UHFFFAOYSA-N
assay   97%
mp   133 °C (dec.)
storage temp.   2-8°C

Description

Application

Reagent for α-acyloxylation of aldehydes and ketones. The reagent is not sensitive to air and moisture.

Benzoylation Reagents Simple Tools for a-Oxygenation of Aldehydes and Ketones

Reactant for preparation of:
• NHC-catalyzed redox esterification and cycloaddition reactions
• Pd/pyrrolidine-catalyzed Tsuji-Trost cyclization of aldehydes
• α-acyloxy ketones via oxyacylation reaction

Packaging

1, 5 g in glass bottle

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Benzoylation Reagents for Chemical Synthesis

The α-hydroxycarbonyl moiety is an important structural motif in organic synthesis and is present in a substantial number of natural products.  A variety of methods have been developed to prepare thi...
Keywords: Dihydroxylations, Epoxidations, Methods, Organic synthesis, Oxidations, Rearrangements, Solvents, Tools, transformation

Ketone and Aldehyde a-Oxygenation

The α-hydroxycarbonyl moiety is an important structural motif in organic synthesis and is present in a substantial number of natural products. A variety of methods have been developed to prepare this...
Aldrich ChemFiles 2007, 7.1, 7.
Keywords: Chemfiles, Dihydroxylations, Epoxidations, Methods, Organic synthesis, Oxidations, Rearrangements, Solvents, Tools, transformation

Related Content

Benzoylation Reagents for Chemical Synthesis

Simple Tools for α-Oxygenation of Aldehydes and Ketones The α-hydroxycarbonyl moiety is an important structural motif in organic synthesis and is present in a substantial number of natural products. ...
Keywords: Dihydroxylations, Epoxidations, Methods, Organic synthesis, Oxidations, Rearrangements, Solvents, Tools, transformation

Peer-Reviewed Papers
15

References

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?