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67000 Aldrich

(R)-1-Ethyl hydrogen 3-methylglutarate

≥99.0% (sum of enantiomers, GC)

Synonym: (R)-Monoethyl 3-methylglutarate, (R)-mono-Ethyl 3-methylglutarate

  • CAS Number 72594-19-5

  • Empirical Formula (Hill Notation) C8H14O4

  • Molecular Weight 174.19

  •  Beilstein Registry Number 1562576

  •  MDL number MFCD00077820

  •  PubChem Substance ID 57652066

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Properties

Related Categories Carbohydrate Chemistry, Carbohydrate Derivatives, Chemical Biology, Chemical Synthesis
InChI Key   KAOCDZQOVPLMID-ZCFIWIBFSA-N
assay   ≥99.0% (sum of enantiomers, GC)
optical activity   [α]20/D −1.3±0.2°, neat
optical purity   enantiomeric ratio: ~98:2 (GC)
refractive index   n20/D 1.437
bp   74-76 °C/0.03 mmHg(lit.)
density   1.076 g/mL at 20 °C(lit.)
storage temp.   2-8°C

Description

Other Notes

Enantiomerically pure monoesters of 3-methylglutarate allow the preparation of important chiral building blocks: synthesis of both enantiomers of β-methyl-γ-valerolactone; synthesis of (R)-3-methylhexanol; Kolbe synthesis of long-chain acids; preparation of a verrucarinic building block

Packaging

1 mL in glass bottle

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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