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673064 Aldrich

(2-Methylallyl)palladium(II) chloride dimer

Synonym: Chloro(2-methylallyl)palladium(II) dimer, Dichlorobis(2-methylallyl)dipalladium, NSC 270885

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium
InChI Key   XVIHZVZZPKOMRE-UHFFFAOYSA-L
mp   168.2-174.0 °C
storage temp.   2-8°C

Description

Analysis Note

Precursor to a Pd(I) catalyst used in cross-coupling of organosilanols.

Packaging

1 g in glass bottle

Application

Catalyst for:
• Asymmetric allylic alkylation reactions
• Suzuki-Miyaura reactions
• Reductive cleavage reactions
• Reaction of alkenyloxiranes with carbon monoxide

Protocols & Applications

Cross-Coupling using Organosilanols as Powerful Nucleophiles

Price and Availability


Essence of Chemistry

Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Organosilanes for Cross-coupling

Over the past several years, Pd-catalyzed cross-coupling of silicon compounds has rapidly gained acceptance as a suitable alternative to more commonly known methods such as: Stille (Sn), Kumada (Mg),...
Aldrich ChemFiles 2006, 6.5, 7.
Keywords: Aldrichimica Acta, Antifungals, Catalysis, Coupling reactions, Cross couplings, Grignard Reaction, Ligands, Metallations, Methods, Protocols, Silylations, Vinylations

Related Content

Organosilanols in Chemical Synthesis

Powerful Nucleophiles for Cross-Coupling Over the past several years, the Pd-catalyzed cross-coupling of silicon compounds (Hiyama coupling) has rapidly gained acceptance as a suitable alternative to...
Keywords: Aldrichimica Acta, Antifungals, Catalysis, Chemfiles, Coupling reactions, Cross couplings, Hiyama Coupling, Hydrosilylations, Ligands, Metallations, Methods, Protocols, Silylations

Peer-Reviewed Papers
15

References

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