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673951 Aldrich

Tricyclopentylphosphine tetrafluoroborate Green Alternative

95%

Synonym: Cyp3HBF4, PCyp3HBF4

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Description

Packaging

1 g in poly bottle

Application

Catalyst for alkane C-H arylation from aryl chlorides

Ligand for ruthenium-catalyzed greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

Used with Ru(cod)Cl dimer to catalyze the dehydrogenative coupling of alcohols and amines to form amide bonds.

General description

Sigma Life Science is committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3261 8 / PGII
WGK Germany 
3

Documents

Certificate of Analysis

Protocols & Articles

Articles

Greener Methods: Catalytic Amide Bond Formation

Amide bonds are one of the most frequently utilized disconnections in organic synthesis. Methods to form this vital functionality are commonly superstoichiometric, leading to considerable waste in th...
Keywords: Amidations, Catalysis, Green chemistry, Organic synthesis, Pharmaceutical

Protocols

Bestmann-Ohira Reagent: Synthesis of Alkynes from Aldehydes Protocol

Acetylene chemistry has been and remains an important constituent element of molecular sciences. Its potential and widespread applications extend from organic synthesis through materials science to b...
Keywords: Bestmann-Ohira Reaction, Building blocks, Chromatography, Click chemistry, Eliminations, Evaporation, Materials Science, Metallations, Organic synthesis, Thin layer chromatography

Catalytic Amide Bond Formation: Greener Methods

The amide bond is one of the most important linkages in organic chemistry and constitutes the key functional group in peptides, polymers, and many natural products and pharmaceuticals.  Amides are us...
Keywords: Amidations, Beckmann Rearrangement, Catalysis, Chromatography, Column chromatography, Ligands, Peptide synthesis, Pharmaceutical, Rearrangements, Schmidt Reaction, transformation

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