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  • 673978 - 2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine

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673978 Aldrich

2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine

Synonym: (3aS,3′aS,8aR,8′aR)-2,2′-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole, (3aS,8aR)-in-pybox

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, PyBOX More...
InChI Key   BZSJUFJXCHHRHW-LUKWVAJMSA-N
optical activity   [α]20/D -375°, c = 1 in dichloromethane (typical)
mp   276-281 °C

Description

Packaging

1 g in glass bottle

250 mg in glass insert

Application

Reactant involved in synthesis of:
• Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
• Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
• Chiral N,N,N-tridentate pybos and pyboxazine ligands

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Safety & Documentation

Safety Information

Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
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