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674702 Aldrich

PEPPSI-SIPr catalyst

Synonym: (1,3-Bis(2,6-diisopropylphenyl)imidazolidene) ( 3-chloropyridyl) palladium(II) dichloride

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium
InChI Key   BWASJRFNPJXAGT-UHFFFAOYSA-L
mp   229-230 °C

Description

Application

Catalyst for C-C and C-N coupling reactions.

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Packaging

1, 5 g in glass bottle

Legal Information

US Patent 7250510

PEPPSI is a trademark of Total Synthesis Ltd.

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

PEPPSI™ Catalyst

Professor Mike Organ, along with Drs. Chris O’Brien and Eric Kantchev, have developed an elegant Pd-NHC catalyst system. The title complex PEPPSI stands for Pyridine-Enhanced Precatalyst Preparation ...
William Sommer
Aldrich ChemFiles 2007, 7.10, 22.
Keywords: Aldrichimica Acta, Aminations, Buchwald-Hartwig amination, Chemfiles, Coupling reactions, Cross couplings, Eliminations, Fischer Indole Synthesis, Ligands, Protocols, Rearrangements, Reductive eliminations

PEPPSI™-IPent for Demanding Cross-Coupling Reactions

Professor Mike Organ and co-workers have developed the PEPPSI™ (Pyridine-Enhanced Precatalyst Preparation Stabilization and Initiation) precatalysts for palladium-catalyzed cross-coupling reactions. ...
Keywords: Aminations, Catalysis, Coupling reactions, Cross couplings, Ligands

Related Content

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Palladium catalyzed cross-coupling reactions have revolutionized the way in which molecules are constructed. From the fields of organic synthesis and medicinal chemistry, to materials science and pol...
Keywords: Catalysis, Coupling reactions, Cross couplings, Materials Science, Medicinal chemistry, Organic synthesis, Polymer science, Type, transformation

PEPPSI Catalysts in Chemical Synthesis

PEPPSI™-IPr: An air- and water-stable catalysts for industrially useful intermolecular cross-coupling reactions, aminations, and intramolecular Heck transformations.
Keywords: Addition reactions, Aminations, Applications, Arylations, Building blocks, Catalysis, Chemfiles, Coupling reactions, Cross couplings, Eliminations, Fischer Indole Synthesis, Grignard Reaction, Ligands, Metathesis, Methods, Nuclear magnetic resonance spectroscopy, Oxidative additions, Rearrangements, Reductions, Reductive eliminations, Suzuki coupling, Suzuki reactions

Peer-Reviewed Papers
15

References

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