Synonym: (R)-3,3′-Diphenyl-2,2′-bi-1-naphthalol, (R)-3,3′-Diphenyl-2,2′-bi-1-naphthol
|Related Categories||Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes More...|
|optical activity||[α]20/D +310°, c = 1 in chloroform|
VANOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.1,2,3
250 mg in glass bottle
Certificate of Analysis
|Precautionary statements||P261-P280-P305 + P351 + P338|
|Personal Protective Equipment||dust mask type N95 (US), Eyeshields, Gloves|
|Hazard Codes (Europe)||Xi|
|Risk Statements (Europe)||37/38-41|
|Safety Statements (Europe)||26-39|
BINOL and its derivatives are some of the mostly widely used classes of ligands in asymmetric synthesis, and are utilized in a broad array of reaction classes including: Diels-Alder, ene, carbonyl ad...
Aldrich ChemFiles 2006, 6.10, 5.
Keywords: Addition reactions, Alkylations, Amidations, Aminations, Asymmetric synthesis, Building blocks, Catalysis, Cycloadditions, Ligands, Organic synthesis, Reductions, Reductive aminations, Substitutions
1. Bao. J. et al. J. Am. Chem. Soc. 118, 3392, (1996)
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