(R)-VAPOL phosphoric acid,
|Related Categories||Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Phosphoric Acids|
Useful chiral Bronsted acid catalyst in the addition of sulfonamides to Boc-activated aryl imines.6
Catalyst involved in:
• Desymmetrization of meso-aziridines1
• Asymmetric aza-Darzens aziridine synthesis2
• Enantioselective ring-opening of mono-and bicyclic N-acyl meso aziridines3
• Condensation of aldehydes with amino benzenesulfonamides4
• Pictet-Spengler reactions5
100, 500 mg in glass bottle
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BINOL-derived phosphoric acids are capable of catalyzing a range of interesting processes of which nucleophilic addition reactions to imine substrates are particularly noteworthy. List and coworkers ...
Aldrich ChemFiles 2007, 7.9, 11.
Keywords: Addition reactions, Aminations, Asymmetric synthesis, Catalysis, Diels-Alder reaction, Nucleophilic additions, Pictet-Spengler reaction, Reductions, Reductive aminations
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