• USA Home
  • 675709 - 2′-(Dicyclohexylphosphino)acetophenone ethylene ketal

EMAIL THIS PAGE TO A FRIEND
675709 Aldrich

2′-(Dicyclohexylphosphino)acetophenone ethylene ketal

97%

Purchase

Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands, Symphos More...
InChI Key   ZQASITYRQOCACA-UHFFFAOYSA-N
assay   97%
mp   85-92 °C

Description

Application

A P-O ligand that in combination with Pd2(dba)3 (cat. no. 328774) provides an active catalyst that effectively cross-couples a variety of arylboronic acids with aryl chlorides containing either electron-rich or electron-poor substituents.

Cocatalyst for:
• Palladium-catalyzed amination reactions
• Palladium/P,O-Ligand-catalyzed Suzuki cross-coupling

Packaging

1, 5 g in glass bottle

Protocols & Applications

Efficient Suzuki Coupling with Symphos Ligands

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Protocols & Articles

Articles

Chiral Phosphoric Acids

BINOL-derived phosphoric acids are capable of catalyzing a range of interesting processes of which nucleophilic addition reactions to imine substrates are particularly noteworthy. List and coworkers ...
Aldrich ChemFiles 2007, 7.9, 11.
Keywords: Addition reactions, Aminations, Asymmetric synthesis, Catalysis, Chemfiles, Diels-Alder reaction, Nucleophilic additions, Pictet-Spengler reaction, Reductions, Reductive aminations

Symphos

A new class of phenyl-backbone derived P,O-ligands (Symphos) were developed by Symyx Technologies in collaboration with professor Fu and coworkers.1 These new ligands proved to be suitable for genera...
William Sommer
Aldrich ChemFiles 2007, 7.10, 11.
Keywords: Catalysis, Chemfiles, Cross couplings, Ligands

Related Content

Symphos Ligands for Efficient Suzuki Cross Coupling

A new class of phenyl-backbone derived P,O-ligands (Symphos) were developed by Symyx Technologies in collaboration with professor Fu and co-workers.1 These new ligands proved to be suitable for gener...
Keywords: Catalysis, Cross couplings, Ligands

Peer-Reviewed Papers
15

References

Set your institution to view full text papers.
Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?