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  • 675792 - (S)-(−)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine

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675792 Aldrich

(S)-(−)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine

97%

Synonym: (S)-P-Phos

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, P-Phos, PhanePhos and BoPhoz Ligands,
InChI Key   JZOSBBLJKXSBBN-UHFFFAOYSA-N
assay   97%
optical activity   [α]20/D -98°, c = 1 in chloroform
mp   261-265 °C

Description

Application

Ligand employed in the asymmetic hydrogenation of ß-keto esters, 2-arylacrylates, aryl ketones , and other substrates.

Packaging

100, 500 mg in glass insert

Legal Information

Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US5886182 and any patents arising therefrom apply.

Price and Availability

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

P-Phos, PhanePhos and BoPhoz™ Ligands

The P-Phos ligand family was developed by Professor Chan of Hong Kong Polytechnic University and licensed to JM CCT in 2002. P-Phos is an atropisomeric biaryl bisphosphine with the unique feature of ...
William Sommer and Daniel Weibel
Aldrich ChemFiles 2008, 8.2, 47.
Keywords: Applications, Asymmetric synthesis, Catalysis, Chemfiles, Hydrogenations, Ligands, Reductions, transformation

Peer-Reviewed Papers
15

References

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