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676098 Aldrich

(S)-VANOL

97%

Synonym: (S)-3,3′-Diphenyl-2,2′-bi(1-naphthalol), (S)-3,3′-Diphenyl-2,2′-bi-(1-naphthol)

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Properties

Related Categories Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes More...
InChI Key   NDTDVKKGYBULHF-UHFFFAOYSA-N
assay   97%
optical activity   [α]20/D -314°, c = 1 in chloroform
mp   199-203 °C

Description

Packaging

250 mg in glass insert

Application

(S)-VANOL is a vaulted biaryl ligand that may be used in the synthesis of coordinated complexes, such as (dppe)Pt(S-VANOL) [dppe= bis(diphenylphosphino)ethane] and (S,S-chiraphos)Pt(S-VANOL) [chiraphos= 2,3-bis(diphenylphosphino)butane].

VANOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Vaulted Biaryl Ligands and BINOL Derivatives

BINOL and its derivatives are some of the mostly widely used classes of ligands in asymmetric synthesis, and are utilized in a broad array of reaction classes including: Diels-Alder, ene, carbonyl ad...
Aldrich ChemFiles 2006, 6.10, 5.
Keywords: Addition reactions, Alkylations, Amidations, Aminations, Asymmetric synthesis, Building blocks, Catalysis, Chemfiles, Cycloadditions, Ligands, Methods, Organic synthesis, Protocols, Reductions, Reductive aminations, Substitutions

Wulff Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Wulff Group – Professor Product Portal
Keywords: Annulations, Asymmetric catalysis, Asymmetric synthesis, Aziridinations, Benzannulations, Catalysis, Ligands, Organic synthesis, Research areas

Peer-Reviewed Papers
15

References

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