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676551 Aldrich

Potassium 2-(3,5-di-tert-butyl-2-hydroxybenzylideneamino)-2,2-diphenylacetate

95%

Synonym: Potassium N-(3,5-di-tert-butylsalicylidene)-2-amino-2,2-diphenylacetate, SALDIPAC

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Other Ligands More...
InChI Key   ZPKNCDGWTMRAKF-QUIZVCAPSA-M
assay   95%
mp   122.2-131.9 °C

Description

Application

Hydroazidation Catalyst for Facile Preparation of Organoazides

SALDIPAC ligand used with Co(BF4)2 (cat. no. 399957) in a hydroazidation of unactivated olefins providing a simple synthesis of alkylazides. The azides, in turn, can be used in a copper-catalyzed cycloaddition with acetylenes providing 1,4-disubstitutedtriazoles.

Packaging

1 g in glass bottle

250 mg in glass bottle

Price and Availability

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Related Content

Hydroazidation Catalyst in Chemical Synthesis

New Hydroazidation Catalyst for Facile Preparation of Organoazides The chemistry of organoazides is exceedingly rich, since the azide functionality reacts with electrophiles, nucleophiles, and dipola...
Keywords: Azide formation, Catalysis, Click chemistry, Cycloadditions, Hydroazidations, Ligands, Reductions, Substitutions, transformation

Peer-Reviewed Papers
15

References

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