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676578 Aldrich

Bis(tri-tert-butylphosphine)palladium(0) Green Alternative

Synonym: Pd(t-Bu3P)2

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Properties

Related Categories 12 Principles Aligned Products, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Greener Alternative Products,
InChI Key   MXQOYLRVSVOCQT-UHFFFAOYSA-N
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   258-272 °C
storage temp.   −20°C

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Application

• Catalyst for Suzuki coupling on a multisubstituted sp3-carbon (eq. 1)
• Catalyst for Stille coupling reaction of aryl chlorides (eq. 2)
• Catalyst for Negishi coupling reaction (eq. 3)
• Catalyst for Heck coupling to form tetrasubstituted olefins (eq. 4)
• Catalyst for Buchwald-Hartwig amination of aryl halide (eq. 5)
• Catalyst for carbonylation of aryl halides with carbamoylsilanes (eq. 6)

Catalyst for greener Heck reaction in TPGS-750-M.

On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors

General description

Sigma Life Science is committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Price and Availability


Essence of Chemistry

Cross-Coupling Guide
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Protocols

Boxed reaction: Heck Reaction in Lipshutz Surfactant

Please consult the Safety Data Sheet for information regarding hazards and safe handling practices.
Keywords: Chromatography, Flash chromatography, Heck Reaction

Heck Kit

Please consult the Safety Data Sheet for information regarding hazards and safe handling practices.
Keywords: Chromatography, Column chromatography, Gas chromatography, High performance liquid chromatography, Thin layer chromatography

Heck Reaction in Water at Room Temperature using TPGS-750-M

TPGS-750-M, DL-α-Tocopherol methoxypolyethylene glycol succinate, is a designer surfactant composed of a lipophilic α-tocopherol moiety and a hydrophilic PEG-750-M chain, joined by an inexpensive suc...
Keywords: Catalysis, Chromatography, Coupling reactions, Cross couplings, Environmental, Flash chromatography, Heck Reaction

Miyaura Borylation Kit

Please consult the Safety Data Sheet for information regarding hazards and safe handling practices.
Keywords: Chromatography, Column chromatography, Gas chromatography, High performance liquid chromatography, Thin layer chromatography

Procedures for Transition-Metal-Catalyzed Cross-Coupling Reactions

TPGS-750-M, DL-α-Tocopherol methoxypolyethylene glycol succinate, is a designer surfactant composed of a lipophilic α-tocopherol moiety and a hydrophilic PEG-750-M chain, joined by an inexpensive suc...
Keywords: Aminations, Buchwald-Hartwig amination, Catalysis, Chromatography, Coupling reactions, Cross couplings, Environmental, Evaporation, Flash chromatography, Heck Reaction, Ligands, Metathesis, Olefin metathesis

Stille Kit

Please consult the Safety Data Sheet for information regarding hazards and safe handling practices.
Keywords: Chromatography, Column chromatography, Gas chromatography, High performance liquid chromatography, Thin layer chromatography

Related Content

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Palladium catalyzed cross-coupling reactions have revolutionized the way in which molecules are constructed. From the fields of organic synthesis and medicinal chemistry, to materials science and pol...
Keywords: Catalysis, Coupling reactions, Cross couplings, Materials Science, Medicinal chemistry, Organic synthesis, Polymer science, Type, transformation

Peer-Reviewed Papers
15

References

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06693 Timestrip Plus -20 °C

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