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  • 680826 - (–)-(S)-N-((R)-3,3-Dimethylbutan-2-yl)-3,3-dimethyl-2-((1-methyl-1H-imidazol-2-yl)methylamino)butanamide

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680826 Aldrich

(–)-(S)-N-((R)-3,3-Dimethylbutan-2-yl)-3,3-dimethyl-2-((1-methyl-1H-imidazol-2-yl)methylamino)butanamide

97%

Synonym: Hoveyda-Snapper Desymmetrization Catalyst

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Organocatalysts
InChI Key   QOCLPFRRAGRCEM-TZMCWYRMSA-N
assay   97%
optical activity   [α]22/D -79°, c = 1 in chloroform
mp   130-134 °C

Description

Application

Useful organocatalyst in the desymmetrization of meso diols.

Packaging

1 g in glass bottle

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
RIDADR 
UN 3335
WGK Germany 
3
Protocols & Articles

Articles

Amino Acids

Barbas and co-workers found the proteinogenic amino acid tryptophan (93660) to be an excellent organocatalyst for the Mannich reaction of hydroxyacetone with a variety of imines performed in DMF (Sch...
Aldrich ChemFiles 2007, 7.9, 10.
Keywords: Aldol reaction, Asymmetric synthesis, Catalysis, Chemfiles, Mannich Reaction, Silylations

Hoveyda-Snapper Catalyst For Desymmetrization Of meso-Diols

 Professors Marc Snapper and Amir Hoveyda at Boston College have recently reported1 the development of an amino-acid-based small molecule 1 capable of promoting asymmetric monosilylation of meso-1,2-...
Aldrich ChemFiles 2007, 7.3, 9.
Keywords: Asymmetric synthesis, Chemfiles, Silylations

Peer-Reviewed Papers
15

References

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