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  • 682381 - Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][3-(2-pyridinyl)propylidene]ruthenium(II)

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682381 Aldrich

Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][3-(2-pyridinyl)propylidene]ruthenium(II)

Synonym: [1,3-Dimesityl-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium(II)

  • CAS Number 802912-44-3

  • Empirical Formula (Hill Notation) C29H35Cl2N3Ru

  • Molecular Weight 597.58

  •  PubChem Substance ID 24885713

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Properties

Related Categories Catalysts for Polymerization, Materials Science, Polymer Science, Reagents for Polymerization, Ring Opening Polymerization More...
InChI Key   LCRADYBTPYSTNK-UHFFFAOYSA-L
mp   190.5-199.0 °C
storage temp.   2-8°C

Description

Other Notes

NO BULK ORDERS

Packaging

100, 500 mg in glass bottle

Legal Information

US Patent Application No. 11/094,102 and foreign equivalents apply. Sale of this product conveys to the buyer a limited-use research license. For full details of this license please see sigma-aldrich.com/materialicense. For questions, please contact us at aldrich@sial.com or Materia at info@material-inc.com.

Application

• Latent initiator, but extremely active once initiated, similar to other 2nd generation catalysts.
• Useful in ROMP applications where longer monomer/catalyst resin handling times are desired.
• Potentially useful in non-ROMP applications as well.
• Enabling metathesis catalyst.

Metathesis: Ruthenium-Based Metathesis Catalysts

• Catalyst for olefin metathesis reactions

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Nanoparticulate Rh and Pd Catalysts

The mild hydrogenation of a variety of arenes—such as benzene, mono- and disubstituted benzenes, naphthalene, and quinoline— has been achieved by using rhodium nanoparticles entrapped in a highly por...
Aldrich ChemFiles 2007, 7.5, 13.
Keywords: Aerobic, Alkylations, Anaerobic, Catalysis, Filtration, Hydrogenations, Oxidations, Reductions, Solvents

Related Content

Metathesis in Chemical Synthesis

Olefin metathesis is now a well-entrenched synthetic technique, and is a powerful method for the clean construction of innumerable classes of chemical architectures. The broadly accepted belief that ...
Keywords: Building blocks, Cross metathesis, Enyne metathesis, Exothermic, Isomerizations, Ligands, Living polymerization, Metathesis, Olefin metathesis, Organic synthesis, Polymerization reactions, Ring opening metathesis polymerisation, Ring-closing metathesis

Peer-Reviewed Papers
15

References

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