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  • 685569 - (11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine

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685569 Aldrich

(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine

Synonym: MonoPhos Ligand

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DSM MonoPhos Phosphoramidites, Privileged Ligands and Complexes More...
InChI Key   OIZQADYWBXZQKE-UHFFFAOYSA-N
optical activity   [α]22/D -282.0°, c = 1 in chloroform
mp   86-94 °C

Description

Packaging

100, 500 mg in glass insert

Legal Information

Sold under license from DSM for research purposes only.

Application

DSM MonoPhos Family of Highly Efficient Privileged Ligands

Price and Availability

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

DSM MonoPhos™ Family - Aldrich ChemFiles 2008, 8.2, 51.

Feringa and co-workers have developed a diverse array of chiral, monodentate phosphoramidites based on the privileged BINOL platform.1 The MonoPhos™ family has exhibited high levels of enantiocontrol...
William Sommer and Daniel Weibel
Aldrich ChemFiles 2008, 8.2, 51.
Keywords: Addition reactions, Alkylations, Aminations, Annulations, Asymmetric synthesis, Catalysis, Chemfiles, Cyclizations, Desymmetrizations, Hydrogenations, Infrared spectroscopy, Ligands, Organic synthesis, Oxidations

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