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691674 Aldrich

2-Dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide

Synonym: XPhos AuNTf2

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold, Gold Catalysts, Gold Complexes More...
InChI Key   GMVGZINKTXAKDT-UHFFFAOYSA-N

Description

Application

Gold Catalysts — 21st Century ′Gold Rush′

• Catalyst for isomerization of allenyl carbinol esters, hydroxy- and methoxycyclization, cycloisomerisation of diynes

Packaging

1 g in glass bottle

250 mg in glass bottle

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Isomerization of Allenyl Carbinol Esters

In 2007, Buzas et al. reported the synthesis of a series of 1,3-butadien- 2-ols from different allenes using a gold complex as catalyst.1 Butadiene building blocks are of interest for Diels-Alder rea...
William Sommer
Aldrich ChemFiles 2009, 9.5, 8.
Keywords: Asymmetric synthesis, Building blocks, Chemfiles, Cycloadditions, Hydrogenations, Methods

Related Content

Gold Catalyst in Chemical Synthesis

Introduction Hashmi, Toste, Echavarren, and Haruta, among others, have fueled the advance of gold into the forefront of transition metal catalysis.1,2 Phosphine ligated gold(I) complexes have risen a...
Keywords: Asymmetric synthesis, Building blocks, Catalysis, Claisen rearrangement, Conia-Ene Reaction, Cyclizations, Cycloadditions, Cycloisomerizations, Cyclopropanations, Deprotonations, Ene reaction, Hydroaminations, Hydrogenations, Isomerizations, Ligands, Rautenstrauch rearrangements, Rearrangements, Reductions, Schmidt Reaction, Substitutions

Peer-Reviewed Papers
15

References

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