Synonym: (S)-(−)-(1,1′-Binaphthalene-2,2′-diyl)bis(diphenylphosphine), (S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene, (S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl, (S)-(−)-BINAP
|Related Categories||Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes More...|
|optical activity||[α]20/D -222, c = 0.5 in benzene|
100, 500 mg in glass bottle
Sold in collaboration with Takasago for research purposes only.
Reactant involved in:
• Enantioselective and diastereoselective unpoled carbonyl allylation
• Syntehsis of organophophine oxides as anittumor agents
• SN2 halogenation of hydroxy groups
• Synthesis of BINAP complexes
• Studies of conformational flexibility of BINAP chelates
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The quest to find chiral catalysts capable of achieving high enantiomeric excess for a variety of asymmetric transformations has been an ongoing endeavor for the past 40 years. One of the most releva...
Keywords: Addition reactions, Arylations, Asymmetric synthesis, Catalysis, Hydrogenations, Ligands, transformation
Introduction The quest to find chiral catalysts capable of achieving high enantiomeric excess for a variety of asymmetric transformations has been an ongoing endeavor for the past 40 years. One of th...
Keywords: Addition reactions, Arylations, Asymmetric synthesis, Building blocks, Catalysis, Epoxidations, Hydrogenations, Hydrosilylations, Ligands, Sharpless Epoxidation, transformation
The preparation of bi-functional organophosphine oxides as potential antitumor agents K. Lam, et al., Eur. J. Med. Chem. 45, 5527-5530, (2011)
Halogenative kinetic resolution of ß-aryloxy cyclic alcohols: chiral BINAP-mediated SN2 displacement of hydroxy groups by chlorides with inversion of stereochemistry E. A. Jaseer, et al., Tetrahedron Asymmetry 21, 2177-2182, (2010)
BINAP: rhodium-diolefin complexes in asymmetric hydrogenation A. Preetz, et al., Tetrahedron Asymmetry 21, 1226-1231, (2010)
Asymmetric catalysis with 7-ring chelate diphosphines: DIOP, BINAP and conformational mobility J. A. Raskatov, et al., Tetrahedron Asymmetry 21, 1737-1744, (2010)
BINAP-AgSbF6 vs. BINAP-AgClO4 complexes as catalysts for the enantioselective 1,3-dipolar cycloaddition of azomethine ylides and alkenes M. Martin-Rodriguez, et al., Synlett 6, 962-966, (2010)
Fieser 10,36 / Fieser 11,53 / Fieser 12,56 / Fieser 13,36 / Fieser 14,38 / Fieser 15,34 / Fieser 16,32 / Fieser 17,36
FT-IR 2 (2), 3323:C / FT-NMR 1 (2), 1663:C / RegBook 1 (2), 2267:N / Structure Index 1, 355:C:4
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
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