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  • 693316 - (S)-2-[[3,5-Bis(trifluoromethyl)phenyl]thioureido]-N-benzyl-N,3,3-trimethylbutanamide

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693316 Aldrich

(S)-2-[[3,5-Bis(trifluoromethyl)phenyl]thioureido]-N-benzyl-N,3,3-trimethylbutanamide

97%

Synonym: (2S)-2-[[[[3,5-Bis(trifluoromethyl)phenyl]amino]thioxomethyl]amino]-N-3,3-trimethyl-N-(phenylmethyl)butanamide

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Jacobsen Thioureas
InChI Key   LTFFYVVCUVYZPE-GOSISDBHSA-N
assay   97%
optical activity   [α]20/D -57.0°, c = 1 in chloroform
mp   147-152 °C

Description

Application

Versatile catalyst for reactions including the Mannich reaction.

Packaging

100, 500 mg in glass insert

General description

(S)-2-[[3,5-Bis(trifluoromethyl)phenyl]thioureido]-N-benzyl-N,3,3-trimethylbutanamide is a chiral thiourea organocatalyst developed by the Jacobsen′s group for asymmetric organic synthesis.

Protocols & Applications

Asymmetric Strecker Reactions using Jacobsen Thioureas

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Related Content

Jacobsen Thioureas in Chemical Synthesis

New Versatile Organocatalysts In 2002, Jacobsen’s group first reported the application of thiourea organocatalyst 1 (693421) in the asymmetric Strecker reaction. Since that initial report, Jacobsen's...
Keywords: Applications, Asymmetric synthesis, Catalysis, Chromatography, Hydrocyanations, Hydrophosphonylations, Mannich Reaction, Organic synthesis, Pictet-Spengler reaction, Strecker synthesis, Type

Peer-Reviewed Papers
15

References

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