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  • 693340 - (2S)-3,3-Dimethyl-2-[[(1R,2R)-2-(2-methyl-5-phenyl-1-pyrrolyl)cyclohexyl]thioureido]-N,N-bis(2-isobutyl)butanamide

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693340 Aldrich

(2S)-3,3-Dimethyl-2-[[(1R,2R)-2-(2-methyl-5-phenyl-1-pyrrolyl)cyclohexyl]thioureido]-N,N-bis(2-isobutyl)butanamide

97%

Synonym: (2S)-3,3-Dimethyl-2-[[[[(1R,2R)-2-(2-methyl-5-phenyl-1H-pyrrol-1-yl)cyclohexyl]amino]thioxomethyl]amino]-N,N-bis(2-methylpropyl)butanamide

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Jacobsen Thioureas
InChI Key   RIAIKFUBJYQDBD-CRXYYGHGSA-N
assay   97%
optical activity   [α]22/D -3°, c = 1 in chloroform
mp   143-147 °C

Description

Application

Catalyst for acyl-Pictet-Spengler and acyl-Mannich reactions.

Protocols & Applications

Asymmetric Strecker Reactions using Jacobsen Thioureas

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Jacobsen Thioureas

Jacobsen’s group has developed a range of chiral thioureas that are versatile and effective organocatalysts. A range of latent nucleophiles can be added to mostly imine-type electrophiles in excellen...
chemfiles volume 7 article 9
Keywords: Asymmetric synthesis, Catalysis, Chromatography, Hydrocyanations, Hydrophosphonylations, Mannich Reaction, Strecker synthesis, Type

Related Content

Jacobsen Thioureas in Chemical Synthesis

New Versatile Organocatalysts In 2002, Jacobsen’s group first reported the application of thiourea organocatalyst 1 (693421) in the asymmetric Strecker reaction. Since that initial report, Jacobsen's...
Keywords: Applications, Asymmetric synthesis, Catalysis, Chromatography, Hydrocyanations, Hydrophosphonylations, Mannich Reaction, Organic synthesis, Pictet-Spengler reaction, Strecker synthesis, Type

Peer-Reviewed Papers
15

References

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