|Related Categories||Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Jacobsen Thioureas|
|optical activity||[α]20/D -88°, c = 1 in chloroform|
|mp||135-138 °C (D)|
Catalyst for the Strecker reaction1
100, 500 mg in glass bottle
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|Precautionary statements||P261-P305 + P351 + P338|
|Personal Protective Equipment||dust mask type N95 (US), Eyeshields, Gloves|
|Hazard Codes (Europe)||Xi|
|Risk Statements (Europe)||36/37/38|
|Safety Statements (Europe)||26-36/37|
Jacobsen’s group has developed a range of chiral thioureas that are versatile and effective organocatalysts. A range of latent nucleophiles can be added to mostly imine-type electrophiles in excellen...
chemfiles volume 7 article 9
Keywords: Asymmetric synthesis, Catalysis, Chromatography, Hydrocyanations, Hydrophosphonylations, Mannich Reaction, Strecker synthesis
New Versatile Organocatalysts In 2002, Jacobsen’s group first reported the application of thiourea organocatalyst 1 (693421) in the asymmetric Strecker reaction. Since that initial report, Jacobsen's...
Keywords: Asymmetric synthesis, Catalysis, Chromatography, Hydrocyanations, Hydrophosphonylations, Mannich Reaction, Organic synthesis, Pictet-Spengler reaction, Strecker synthesis
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