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695815 Aldrich

Bis(4-methylphenyl)chlorophosphine

96%

Synonym: P,P-Bis(4-methylphenyl)-phosphinous chloride, Chlorodi-p-tolylphosphine

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors
InChI Key   BJBXRRHIBSXGLF-UHFFFAOYSA-N
assay   96%
refractive index   n20/D 1.501
density   1.1 g/mL at 25 °C

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Application

Reactant for synthesis of:
• Palladium catalysts for C-C bond forming cross-coupling reactions
• Ligands for nickel(0)-catalyzed isomerization reactions
• Phosphinosulfonamide nickel complexes for oligomerization reactions

Reactant for:
• Pd-catalyzed intramolecular asymmetric allylic amination and ring-closing metathesis
• Phosphinylation reactions

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN 3265 8 / PGIII
WGK Germany 
3
Protocols & Articles
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