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700223 Aldrich

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III)

97%

Synonym: Mn(TMHD)3, Mn(dpm)3, Shenvi Hydrogenation Catalyst, Tris(dipivaloylmethanato)manganese

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Manganese, Non-Precious Metal Catalysis
InChI Key   ORZPLLPBZHORSD-LWTKGLMZSA-K
assay   97%
mp   160-170 °C

Description

Packaging

1 g in glass bottle

Application

Catalyst for:
• Intramolecular Diels-Alder reactions
• Single electron donor for excess electron transfer studies in DNA
• Enantioselective synthesis
• Borylation reactions
• Hydrohydrazination and hydroazidation
• Oxidative carbonylation of phenol

Notably, this non-precious metal catalyst can be used to obtain the thermodynamic hydrogenation product of olefins, selectively.

Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles
Related Products

Technical Service:

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