|Related Categories||Chemical Synthesis, Grignard Reagents, Heteroaryl, Organometallic Reagents|
|concentration||1.0 M in THF/toluene|
|20 % (w/w)|
|density||0.96 g/mL at 25 °C|
4×25, 100, 500 mL in Sure/Seal™
Product of Rockwood Lithium
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0.5 M in toluene
1.3 M in THF
0.6 M in THF
Certificate of Analysis
|Symbol||GHS02, GHS07, GHS08|
|Precautionary statements||P210-P261-P281-P305 + P351 + P338|
|Supplemental Hazard Statements||May form explosive peroxides.|
|Hazard Codes (Europe)||F,C|
|Risk Statements (Europe)||63-11-14-19-34-37|
|Safety Statements (Europe)||16-26-36/37/39-45|
|RIDADR||UN 3399 4.3/PG 1|
|Flash Point(F)||5 °F|
|Flash Point(C)||-15 °C|
From our library of Articles, Sigma-Aldrich presents Discover Reagents for Selective Metalations and Additions from Sigma-Aldrich
Aldrich ChemFiles 2009, 9.6, 11.
While halogen-metal exchange reactions are among the most common methods for preparing organometallic reagents, Li-halogen exchange reactions typically require low temperatures and offer limited comp...
Dr. Josephine Nakhla
Chemfiles Volume 10 Article 1
Keywords: Addition reactions, Catalysis, Deprotonations, Eliminations, Grignard Reaction, Metallations, Nucleophilic additions, Reductions, transformation
Over the last several years, Knochel and coworkers have reported reagents for selective metalation, deprotonation and nucleophilic additions. These reagents have transformed the field, allowing for u...
Keywords: Addition reactions, Aminations, Catalysis, Cross couplings, Deprotonations, Eliminations, Grignard Reaction, Metallations, Methods, Nucleophilic additions, Reductions, Size-exclusion chromatography, transformation
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