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  • 708461 - [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride

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708461 Aldrich

[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride

Synonym: [PdCl2{(R)-4-tolylbinap}]

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Properties

Related Categories Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes More...
InChI Key   ADMKISPNGKUJAU-UHFFFAOYSA-L
mp   >300 °C

Description

Packaging

100, 500 mg in glass insert

Application

Catalyst for:
• Enantioselective preparation of hydroxydicarbonyls via aldol addition of pyruvates and diketones with ketene thioacetal
• Stereoselective aldol condensation using trimethyl[[(phenyl)ethenyl]oxy]silane and benzaldehyde as reactants
• Stereoselective preparation of naphthalenols via alkylative ring opening of oxabenzonorbornadienes with dialkylzinc

Reactant for:
• Preparation of palladium bis(diphenylphosphino)binaphthyl aqua mononuclear and hydroxo-bridged dinuclear complexes

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
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